Interested Article - Браун, Герберт Чарлз

???????? ????? ?????? (??? ??? ???????? — ??????? ????????? ; 22 ??? 1912 — 19 ??????? 2004 ) — ???????????? ????? -???????, ??????? ??????????? ?????? ?? ????? ( 1979 ).

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??????? ????? ????? ??????? ? 1912 ???? ??????? , ? ????? ?????? ?? ???????? — ???????? ???? ????????? (?????. ??????????) ? ??????? ?????? ??????????. ?? ??? ?? ???????????? ????? ? ?????? ?? ??????? ?????. ??? ???????? ????????????? ? ?????? ? 1908 ????, ? ????? 6 ??? ????????? ? ????????? ???? ?????? ?????????? ? ?????? ? 1914 ????. ??? ???? ?????? ??? ????? ????????? ? ??????, ??? ?? ??? ?? ?????? ???????? ? ??????? ? 1943 ???? .

? 1926 ???? ???? ???? ???????? ??????, ? ????? ???????? ????????? ????? ? ??????????? ???????? ????????? ??????? ???????. ???????? ?? ???, ? 1930 ???? ?? ??????? ?????, ? 1935 ???? — ????-???????-???????, ??? ???????????? ?? ????? ??????? ?????, ????? ??????, ? ??? ????? ???, ? 1936, ??????? ??????? ????????? ???????????? ???? ? ????????? ???????????? , ?????????? ? ?? ???? ????? ?? ??????? ??????? ???????? ????? ? ??????? .

???? ???????????? ??? ?????????? ??????????? ????? ???????? ? ??????????? ?. ?. ?????????? ? ????????? ????????????. ? 1939 ???? ??????? ????? ??????? ?????????? ???????, ? ??? ?? ????? ?? ??????? ?? ???? ??????.

????? ??????? ????? ?????? ??????????? ????????? ?????????? ???????????? ? ?????? ?. ?. ??????, ??? ????????? ????????????? ????????????, ??????????????????? ? ??????? ????????-???????????? ?????????. ? 1941 ???? ????? ????????????? ? ?????? ?. ?. ?????????? ? ???????? ?????????? ?? ????????? ????????????. ??? ?? ?????????? ?????? ?????????? ? ????????? ???????? ? ????????? ??????????? ? ?????? ??????????? ???????????. ? 1943 ???? ????? ??????? ????????? ?????????? ?????????? ? ???????????? ????? ? ???????? .

??? ???????????? ??????? ? ???????? ?????????? ???????????? ??????? ?????? ????????????? ? F-, Br-, I- ???????????, ????? ??? ???????? ????????? ? ?????? ??????????.

????? ??? ??????? ?? ??????? ? 1946 ????, ? 1947 ???? ?. ???? ????????? ???????? ?????? ?? ????????? ?????????? ? ???????????? ??????, ??? ?? ????????? ???? ?????? ??? ???????????? ????????? ? ?????????????? ????????????? ??????????, ??? ??????? ? ????????? ???????? ???????????????? ????????? ? ?. ?. ????? ??? ? 1956 ???? ? ??? ????????????? ?????? ? ?. ?. ????????? ? ?. ????????? ? 1964 ????. ? 1959 ???? ??????? ????? ??? ??????? ?? ????????? ?????????? ? ??????????? R.B. Wetherill ??? ????????? ??????, ? ? 1960 ???? ????? ????????? ????????????????? ? ????????????????? ????????????. ? 1978 ???? ?? ????? ?? ?????? ? ??????? ?????? ???????????? ?????????? ? ????????. 19 ??????? 2004 ???? ? ???????? 92 ??? ??????? ????? ???? ?? ?????????? ????????.

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??????? ???????????? ?????? ? ??????? ????? ???? ???????? ?????????? ?????????? ?????? ?????? ?. ?. ??????????? ; ??????????????? ???????????? ? ?????????? ?? ?????????????? ???????? ??????? ???????????? ?????????? ? ??????? ?????????? ?????? ? ?????? ????????? ? ???? ??????????? ? ?????????????; ???????? ???????????????? ? ??????????? ???????? ???????????? ????????, ?? ?????? ????? ??????; ???????? ?????????????? ????????????????, ????????????????? ? ?????? ??????? ??? ???????? ????????????? ????? ???????-??????? . ??? ?? ????? ?????????? ?????? ?????????? ? ????????? ???????? ? ????????? ??????????? ? ?????? ??????????? ???????????; ???????? ??????? ?????? ????????????? ? F-, Br-, I- ???????????, ????? ??? ???????? ????????? ? ?????? ??????????; ???????? ?????????? ??????? ??????????? ????????? ? ???? ? ???? ?????????? ??????????? ?????????? ? ????? ?????? ??????????? ??????????? ?????????; ?????????? ??????? ????????????????; ?????? ????????-?????????????? ?????-????????? ????????????? ????? ? ?????????????. .

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??????? ????? ?????????? ??? ?????? ???????, ???????? ?? ????????? ????????????. ????? ?? ??? ???????? ??????????? ??????????, ?????? — ??????? ????????? ??? ??????? ??????????. ? ??????????? ???????????? ??????????, ????? ?????????? ??????????? ?????????? ????????? ????????????, ?? ??????? ??????????. ?? ?????????? ??????, ????? ????? ????????? ??????? ????????????? ?????????, ????? ??? ??????????? ? ???????????????? ???????, ????? ????? ?????????????, ? ?????????????? ?????????????, ??????? ???????? ??? ???????????? ???????????????? ???????, ?? ???????? ???????? ??????. ????? ??? ??????????? ??????????? ????????????? ?????????????? ???????? ? ??? ???????, ????? ????? ?????? ?? ????? ?????????? ? ????? ??????? ????????? ???????????????? ??????????. ?????? ?????? ??????????? ???, ??? ? ??????? ?? ??????????? ? ????????-?????????? ??????????????????? ??????????, ??????????? ??????? ? ?????????????. ?? ???? ??????? ?????? ????? ?????? ?????? ???? ??????? ?? ???????? ??? ?????????? ?????????????? ????????.

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????? ??????????? ????? 1300 ??????? ??????????, ????????? ????, ? ????? ????????? ???????? ????????, ? ??????? ?? ???????? ????? 20 ?????????? ? ???.

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H. C. Brown. Organic Syntheses: Via Boranes. Milwaukee: Aldrich Chemical Co, vol. 1, 1975.
H. C. Brown. The Nonclassical Ion Problem (with comments by P. von Schleyer). New York: Plenum Press, 1977.
H. C. Brown, M. Zaidlewicz. Recent Developments, Organic Syntheses: Via Boranes. Milwaukee: Aldrich Chemical Co, vol. 2, 2001.
H. C. Brown, A. Suzuki. Suzuki Coupling, Organic Syntheses: Via Boranes. Milwaukee: Aldrich Chemical Co, vol. 3, 2003.

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?????? ???????? (1955)
?????? ??????? ????????????? ??????????? ???????? (1959)
?????? ??????? ???????
???????????? ?????? «?? ??????? ??????????» ????????????? ???????? ????? (1969)
?????? ??????? ????????? ???????? ????????????? ???????????? (1973)
?????? ??????? ???????? ??????????????? ????????? (1978)
?????? ?????????? ???????? ??????????? ??????????? ???????? (1978)
??????????? ?????? ?? ????? «?? ?????????? ????? ??????? ????????????? ??????? ??????? ???- ? ???????????????? ??????????» ( 1979 )
?????? ??????? ????????????? ??????????? ???????? (1981)
?????? ??????? (1982)
??????? ?????? ????????????? ????????? ??????? (1985)
(1987)
????????????? ??????? (??????): ????? ??????????? ??????, ??????? ? ?????????? ?????? (1989)

?????? ??????? ?????? ???????????? ???????? ???? ??? (1957) ? ???????????? ???????? ???? ? ????????, ???????? ?????? ??????????? ??????????? ????????, ??????????? ?????? ????????? ???????????? ???????? ???? (1978).

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? 1998 ???? ???????????? ?????????? ????????? ???? ??????? ?????? ???????? ?. ?????? ?? ?????????? ???????????? ????????????? ??????? . ? ???? ???????? ????? ??? ???????????? ? ??????? ? ???????? Purdue University, ???? ?? ???? ???????? ?????????? ???????? ??? ?????? Brown Building, ? ??? ??????? ???? ????????????? ? ?????????? ??????????? ????? ?. ?. ??????.

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??????? ????? ??????? ???????????? ? ?????????? ??????? ???, ??????? ?????????? ??????????? ? ??????????????. ? ????? ????????????????? ?????? ????? ?????? ?? ?????? ???????? ? ?????????? ??????, ? ????? ?????? ? ?????????????? ? ?????????? ?????????????. ??? ??????? ???????: «? ???? ???? ??? ????? ?? ?????». ????? ??????????? ???????? ????????????, ???????????? ? ?????????? ??? ?????????? ???????????? ????????????? ???????? ??????????? ????????, ? ????? ? ????????????? ??????????? ???????????.

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Brown H. C., Schlesinger H. I., Burg A. B. Hydrides of boron. XI. The reaction of diborane with organic compounds containing a carbonyl group // J. Am. Chem. Soc., 1939, v. 61, p. 673—680
Herbert C. Brown, Asymmetric carbon-carbon bond formation via .beta.-allyldiisopinocampheylborane. //J. Am. Chem. Soc., 1983, 105 (7), pp 2092—2093
H. C. Brown and P. Veeraraghavan Ramachandran, Sixty Years of Hydride Reductions // ACS Symposium Series, 1996, Vol. 641, Chapter 1, pp 1-30 ?? 15 ????? 2022 ?? Wayback Machine
Herbert C. Brown, Krishna S. Bhat, Ramnarayan S. Randad , Allyl- and crotylboration of .alpha.-chiral aldehydes with diisopinocampheylboron as the chiral auxiliary // J. Org. Chem., 1989, 54 (7), pp 1570—1576
Herbert C. Brown, K. J. Morgan, Frank J. Chloupek , tructural Effects in Solvolytic Reactions. I. The Role of Equilibrating Cations in Carbonium Ion Chemistry // J. Am. Chem. Soc., 1965, 87 (10), pp 2137—2153
Herbert C. Brown, Min-Hon. Rei, Comparison of the Effect of Substitutents at the 2-Position of the Norbornyl System with Their Effect in Representative Secondary Aliphatic and Alicyclic Derivatives. Evidence for the Absence of Nonclassical Stabilization of the Norbornyl Cation // J. Am. Chem. Soc., 1964, 86 (22), pp 5008-5010
Herbert C. Brown , The energy of the transition states and the intermediate cation in the ionization of 2-norbornyl derivatives. Where is the nonclassical stabilization energy? // Acc. Chem. Res., 1983, 16 (12), pp 432—440 ?? 6 ??? 2021 ?? Wayback Machine
Herbert C. Brown, M. Ravindranathan, Edward N. Peters, C. Gundu Rao, Morris M. Rho, Structural effects in solvolytic reactions. 22. Effect of ring size on the stabilization of developing carbocations as revealed by the tool of increasing electron demand // J. Am. Chem. Soc., 1977, 99 (16), pp 5373-5378
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H. C. Brown, M. D. Taylor and M. Gerstein. Acid-base studies in gaseous systems. Precise dissociation measurements. // J.Am. Chem. Soc. 1944, pp. 431—435

H. C. Brown, H. I. Schlesinger and A. B. Burg. Hydrides of boron. XI. The reaction of diborane with organic compounds containing a carbonyl group. // J. Am. Chem. Soc. 1939 V. 61, pp. 673—680

H. C. Brown, H. I. Schlesinger and A. E. Finholt. New developments in the chemistry of diborane and of the borohydrides. The preparation of sodium borohydride by the high temperature reaction of sodium hydride with borate esters. // J. Am. ?hem. Soc. 1953, V. 75, pp. 205—209

H. C. Brown, B. C. Subba Rao. A new technique for the conversion of olefins into organoboranes and related alcohols. // J. Am. Chem. Soc. 1956, V. 78, pp.5694-5695

H. C. Brown, G. Zweifel. The hydroboration of acetylenes—a convenient conversion of internal acetylenes to cis olefins of high purity and of terminal acetylenes to aldehydes. // J. Am. Chem. Soc. 1959, V. 81, pp.1512

H. C. Brown, B. C. Subba Rao. Hydroboration. The reduction of organic compounds by diborane, an acid-type reducing agent. // J. Am. Chem. Soc. 1960, V. 82, pp. 681—686

H. C. Brown, N. R. Ayyangar and G. Zweifel. Hydroboration. Reaction of diisopinocamphenylborane with representative cis-acyclic, cyclic, and bicyclic olefins. Convenient synthesis of optically active alcohols and olefins of high optical purity and established configuration. // J. Am. Chem. Soc. 1964, V. 86, pp. 397—403

H. C. Brown, P. V. Ramachandran. Asymmetric reduction with chiral organoboranes based on alpha-pinene. // Acounts. Chem. Res. 1992, V. 25, pp.16-24

H. C. Brown, M. Zaidlewicz. Recent Developments, Organic Syntheses: Via Boranes. // Aldrich Chemical Co, 2001, V. 2

H. C. Brown, A. Suzuki. Suzuki Coupling, Organic Syntheses: Via Boranes. // Aldrich Chemical Co, 2003, V. 3

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